TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)COBALT (III)

For research use only. Not for therapeutic Use.

  • CAT Number: M055445
  • CAS Number: 14877-41-9
  • Molecular Formula: C33H57CoO6
  • Molecular Weight: 608.74
  • Purity: ≥95%
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Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)cobalt(III)(Cat No.:M055445), commonly abbreviated as Co(TMHD)₃, is a cobalt(III) coordination complex featuring three bulky β-diketonate ligands. These ligands provide strong chelation and steric protection, enhancing the thermal stability and volatility of the complex. It is widely used as a metal precursor in chemical vapor deposition (CVD) and atomic layer deposition (ALD) processes for fabricating cobalt-containing thin films in microelectronics. Co(TMHD)₃ also finds applications in materials science, catalysis, and the preparation of magnetic or conductive coatings. Its air stability and solubility in organic solvents make it suitable for advanced material fabrication.


CAS Number 14877-41-9
Molecular Formula C33H57CoO6
Purity ≥95%
Storage Store at -20C
IUPAC Name cobalt(3+);(Z)-2,2,6,6-tetramethyl-5-oxohept-3-en-3-olate
InChI InChI=1S/3C11H20O2.Co/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/q;;;+3/p-3/b3*8-7-;
InChIKey UJRJNARBHKKZST-LWTKGLMZSA-K
SMILES CC(/C(=C/C(=O)C(C)(C)C)/[O-])(C)C.CC(/C(=C/C(=O)C(C)(C)C)/[O-])(C)C.CC(/C(=C/C(=O)C(C)(C)C)/[O-])(C)C.[Co+3]
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