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Reference Standards>Chiral phosphine ligands> (R)-4-tert-Butyl-2-[(SP)-2-(diphenylphosphino)ferrocenyl]-2-oxazoline
For research use only. Not for therapeutic Use.
(R)-4-tert-Butyl-2-[(SP)-2-(diphenylphosphino)ferrocenyl]-2-oxazoline(Cat No.:M124908)is a planar chiral ferrocenyl-based ligand combining an oxazoline ring and a diphenylphosphino moiety. This compound is widely used in asymmetric catalysis, especially in transition metal-catalyzed enantioselective reactions such as hydrogenation, allylic substitution, and cyclopropanation. The presence of both axial and central chirality imparts high enantioselectivity and tunability in catalytic systems. Its rigid ferrocenyl backbone and bulky tert-butyl group further enhance stereocontrol. It is typically used to form stable complexes with metals like palladium, rhodium, and iridium in academic and industrial research.
CAS Number | 1226898-27-6 |
Molecular Formula | C29H30FeNOP |
Purity | ≥95% |
Storage | Store at -20°C |
InChI | InChI=1S/C24H25NOP.C5H5.Fe/c1-24(2,3)22-17-26-23(25-22)20-15-10-16-21(20)27(18-11-6-4-7-12-18)19-13-8-5-9-14-19;1-2-4-5-3-1;/h4-16,22H,17H2,1-3H3;1-5H;/t22-;;/m0../s1 |
InChIKey | PIKHGGNXFQMMMR-IKXQUJFKSA-N |
SMILES | CC(C)(C)[C@@H]1COC(=N1)[C]2[CH][CH][CH][C]2P(C3=CC=CC=C3)C4=CC=CC=C4.[CH]1[CH][CH][CH][CH]1.[Fe] |
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