For research use only. Not for therapeutic Use.
(DHQD)₂PHAL(CAT: M095268), or (−)-diquinidine phthalazine, is a chiral phase-transfer catalyst derived from diquinidine and phthalazine. It appears as a white to off-white solid and is widely used in asymmetric synthesis, particularly in Sharpless asymmetric dihydroxylation and related enantioselective oxidative transformations. The catalyst’s rigid, chiral framework enables high enantioselectivity by controlling the spatial orientation of substrates during reaction, making it valuable in the synthesis of optically pure alcohols, diols, and other chiral building blocks.
| CAS Number | 140853-10-7 |
| Molecular Formula | C48H54N6O4 |
| Purity | ≥95% |
| Storage | -20°C |
| IUPAC Name | 1,4-bis[(S)-[(2R,4S,5R)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]-(6-methoxyquinolin-4-yl)methoxy]phthalazine |
| InChI | InChI=1S/C48H54N6O4/c1-5-29-27-53-21-17-31(29)23-43(53)45(35-15-19-49-41-13-11-33(55-3)25-39(35)41)57-47-37-9-7-8-10-38(37)48(52-51-47)58-46(44-24-32-18-22-54(44)28-30(32)6-2)36-16-20-50-42-14-12-34(56-4)26-40(36)42/h7-16,19-20,25-26,29-32,43-46H,5-6,17-18,21-24,27-28H2,1-4H3/t29-,30-,31-,32-,43+,44+,45-,46-/m0/s1 |
| InChIKey | YUCBLVFHJWOYDN-HVLQGHBFSA-N |
| SMILES | CCC1CN2CCC1CC2C(C3=C4C=C(C=CC4=NC=C3)OC)OC5=NN=C(C6=CC=CC=C65)OC(C7CC8CCN7CC8CC)C9=C1C=C(C=CC1=NC=C9)OC |
| Chemistry Calculators | Dilution Calculator In vivo Formulation Calculator Molarity Calculator Molecular Weight Calculator Reconstitution Calculator |
