Home
>
Catalysts and Ligands>Chiral nitrogen ligands>
>
(4S,4'S)-2,2'-((Phenylphosphanediyl)bis(2,1-phenylene))bis(4-benzyl-4,5-dihydrooxazole)
For research use only. Not for therapeutic Use.
(4S,4’S)-2,2′-((Phenylphosphanediyl)bis(2,1-phenylene))bis(4-benzyl-4,5-dihydrooxazole)(CAT: L000900) is a chiral, bidentate ligand featuring a bis-oxazoline framework linked through a phenylphosphine core. This compound is widely used in asymmetric synthesis, especially as a chiral ligand in transition metal catalysis, due to its rigid, sterically demanding structure and ability to induce chirality. The (4S,4’S) stereochemistry and oxazoline rings contribute to its effectiveness in enantioselective transformations, providing high selectivity in catalytic reactions such as asymmetric hydrogenation, cycloadditions, and cross-coupling reactions. The phenylphosphine backbone enhances its binding affinity to metal centers, making it a valuable tool in the synthesis of enantiomerically pure compounds. This ligand is particularly relevant in pharmaceutical research and fine chemical synthesis, where precise control over stereochemistry is crucial.
Catalog Number | L000900 |
CAS Number | 2368937-52-2 |
Molecular Formula | C38H33N2O2P |
Purity | ≥95% |
IUPAC Name | bis[2-[(4S)-4-benzyl-4,5-dihydro-1,3-oxazol-2-yl]phenyl]-phenylphosphane |
InChI | InChI=1S/C38H33N2O2P/c1-4-14-28(15-5-1)24-30-26-41-37(39-30)33-20-10-12-22-35(33)43(32-18-8-3-9-19-32)36-23-13-11-21-34(36)38-40-31(27-42-38)25-29-16-6-2-7-17-29/h1-23,30-31H,24-27H2/t30-,31-/m0/s1 |
InChIKey | HSRGLAMKLMUNJI-CONSDPRKSA-N |